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Oct 30, 2025

Yuav ua li cas lub ntuj tiv thaiv txheej ntawm weathering steel tiv thaiv tus hlau los ntawm corrosion?

1. Lub cev thaiv kev: thaiv cov tshuaj corrosive

Lub ntsej muag patina yog qhov ntom ntom, ua kom tiav txheej ua lag luam crystalline (piv txwv li, fe₃o₄), thiab enriced alloy ntsiab (CU, CR, P) los ntawm cov cua hlau. Nws cov teebmeem ntawm lub cev muaj:
 

Tsawg porosity: Tsis zoo li xoob, xeb xeb ntawm cov pa roj carbon hlau, lub patina lub nruj nreem ntim cov qauv siv lead ua kom tsawg heev. Qhov no tiv thaiv cov dej noo ua kua (nag, lwg) thiab gaseous oxygen los ntawm kev ua kom ob qho tib si noo noo thiab oxygen los pib lub tshuab hluav taws xob (fe →+ 2 e⁻).

Polledant Kuj: Alloy Cov Ntsiab Lus xws li CR thiab CU hauv Patina muaj kev cuam tshuam los ua cov tebchaw ruaj khov (piv txwv li, cu₂o) uas ntxiv txo cov txheej txheej permeability. Cov tebchaw no xa tawm cov phom sij ions (piv txwv li, yog li cov ntug dej hiav txwv ntsev, yog li kev ua kom huv si los ntawm kev rhuav tshem cov oxides.

2. Tshuaj Kev Cai: inhibiting Electrochemical Corrosion

Corrosion ntawm cov hlau yog cov txheej txheem electrochemical (anode: tus hlau oxidizes; cathergen txo). Lub patina kev cuam tshuam cov txheej txheem no los ntawm kev cai tshuaj lom:
 

Kev Hloov Hluav Taws Xob Hluav Taws Xob: Peb Patina ua raws li cov hluav taws xob insulator. Nws ua rau cov hluav taws xob hluav taws xob ntawm lub tshuab hluav taws xob ntawm anodic (oxidizing) steel saum npoo av thiab cathodic) oxygen rau saum huab cua, ua rau muaj cov pa hluav taws xob uas tsav corrosion.

Stabilizing hlau ions: Patina cuab ntxiab feed (tsim los ntawm cov hlau oxidation) nyob rau hauv nws cov qauv, tiv thaiv cov lus no los ntawm kev ua kom noo thiab tsiv teb tsaws chaw. Instead, Fe²⁺ is oxidized to more stable Fe³⁺, which integrates into the patina's crystal lattice-strengthening the layer rather than causing further rusting.

3. Tus kheej -}} kho: kho kev puas tsuaj me

Tsis zoo li cov txheej txheem dag dag zog (piv txwv li, xim) uas tev tawm mus tas li, lub patina tau txwv tus kheej - lub sij hawm tiv thaiv:
 

Thaum lub patina loj hlob me me tawg los yog khawb (piv txwv li, los ntawm kev cuam tshuam me), cov qauv tshiab tawm tsam sai nrog huab cua thiab ya raws.

Tus muaj xeb tshiab tsim ntawm lub vev xaib puas yog nplua nuj nyob hauv cov hlau cov ntsiab (CU, CR, P). Lub sijhawm dhau los, qhov kevcai tshiab no nrog cov nrib pleb, sau cov kab nrib pleb thiab rov ua kom muaj kev tiv thaiv.

Qhov no tus kheej -} hehoinging relies (40-60% rh): tsis txaus kom ntxuav tawm cov oxides tshiab ua ntej lawv muab tso ua ntej.

Qhov tseem ceeb sib txawv los ntawm tib neeg cov hlau

Cov khoom siv roj carbon hlau zoo tib yam xoob, flaky xeb uas peels tawm yooj yim. Qhov no nthuav tawm cov tshiab steel saum npoo rau corrosion, tsim lub "voj voog ntawm rowing thiab tev" uas accelerates degradation. Hauv kev sib piv, huab cua ua hlau lub patina yogadherent, ntom, thiab tus kheej -} kho{{0- nws tsis tev, thiab es tsis txhob muaj ntau tus tiv thaiv dhau lub sijhawm (yog tias ib puag ncig cov xwm txheej yog tsim nyog).
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